Natural gas

Natural gas (also gas, methane gas or fossil gas) is a fossil fuel, naturally occurring in geological formations. Typically, the gas is a mix of gaseous hydrocarbons, primarily methane (95%), small amounts of higher alkanes, and traces of carbon dioxide and nitrogen, hydrogen sulfide and helium. Methane is a colorless and odorless gas, and, after carbon dioxide, is the second-greatest greenhouse gas that contributes to global climate change. Because natural gas is odorless, a commercial odorizer, such as methanethiol, that smells of hydrogen sulfide (rotten eggs) is added to the gas for the ready detection of gas leaks.

Natural gas is a fossil fuel that is formed when layers of organic matter (primarily marine microorganisms) are thermally decomposed under oxygen-free conditions, subjected to intense heat and pressure underground over millions of years. The energy that the decayed organisms originally obtained from the sun via photosynthesis is stored as chemical energy within the molecules of methane and other hydrocarbons. Most natural gas is collected from underground geological formations, often alongside other fossil fuels like coal and oil (petroleum). Natural gas is often a byproduct of petroleum production, where it can either be vented without burning, flared (burned off) or collected.

The extraction and consumption of natural gas is a major industry. According to a 2025 IEA report, demand has increased in recent years. When burned for heat or electricity, natural gas emits fewer toxic air pollutants, less carbon dioxide, and almost no particulate matter compared to other fossil fuels. However, the natural gas industry is one of the largest drivers of climate change: gas venting and unintended fugitive emissions throughout the supply chain can result in natural gas having a similar or greater carbon footprint to other fossil fuels overall. Much of this is driven by methane's greater effect on radiative forcing. Globally, new installed natural gas infrastructure is one of the largest sources of increased greenhouse gas emissions for energy production. To meet climate goals, 2023 IPCC Sixth Assessment report concluded that new fossil gas infrastructure is only suitable under very specific conditions with carbon capture and fugitive gas prevention technologies, otherwise it risks emissions overshoot or becoming stranded assets.

Before natural gas can be burned as a fuel or used in manufacturing processes, it almost always has to be processed to remove impurities such as water. The byproducts of this processing include ethane, propane, butanes, pentanes, and higher molecular weight hydrocarbons. Hydrogen sulfide (which may be converted into pure sulfur), carbon dioxide, water vapor, and sometimes helium and nitrogen must also be removed. While natural gas is frequently transported in a gaseous state in gas pipelines, inter-country transportation and long-term storage of natural gas was not widely available until the widespread adoption of liquefied natural gas.

Natural gas is measured in standard cubic meters or standard cubic feet. The density compared to air ranges from 0.58 (16.8 g/mole, 0.71 kg per standard cubic meter) to as high as 0.79 (22.9 g/mole, 0.97 kg per scm), but generally less than 0.64 (18.5 g/mole, 0.78 kg per scm). For comparison, pure methane (16.0425 g/mole) has a density 0.5539 times that of air (0.678 kg per standard cubic meter).

Name

In the early 1800s, natural gas became known as "natural" to distinguish it from the dominant gas fuel at the time, coal gas. Unlike coal gas, which is manufactured by heating coal, natural gas can be extracted from the ground in its native gaseous form. When the use of natural gas overtook the use of coal gas in English-speaking countries in the 20th century, it was increasingly referred to as simply "gas". However, it is not to be confused with gasoline, which is also shortened in colloquial usage to "gas", especially in North America.

In order to highlight its role in exacerbating the climate crisis, however, many organizations have criticized the continued use of the word "natural" in referring to the gas. These advocates prefer the term "fossil gas" or "methane gas" as better conveying to the public its climate threat. A 2020 study of Americans' perceptions of the fuel found that, across political identifications, the term "methane gas" led to better estimates of its harms and risks.

History

Natural gas can come out of the ground and cause a long-burning fire. In ancient Greece, the gas flames at Mount Chimaera contributed to the legend of the fire-breathing creature Chimera. In ancient China, gas resulting from the drilling for brines was first used by about 400 BC. The Chinese transported gas seeping from the ground in crude pipelines of bamboo to where it was used to boil salt water to extract the salt in the Ziliujing District of Sichuan.

Natural gas was not widely used before the development of long distance pipelines in the early 20th century. Before that, most use was near to the source of the well, and the predominant gas for fuel and lighting during the industrial revolution was manufactured coal gas.

The history of natural gas in the United States begins with localized use. In the seventeenth century, French missionaries witnessed the American Indians setting fire to natural gas seeps around Lake Erie, and scattered observations of these seeps were made by European-descended settlers throughout the eastern seaboard through the 1700s. In 1821, William Hart dug the first commercial natural gas well in the United States at Fredonia, New York, United States, which led in 1858 to the formation of the Fredonia Gas Light Company. Further such ventures followed near wells in other states, until technological innovations allowed the growth of major long distance pipelines from the 1920s onwards.

By 2010, 66,000 km3 (16,000 mi3) (or 8%) had been used out of the total 850,000 km3 (200,000 mi3) of estimated remaining recoverable reserves of natural gas.

Natural gas

In the 19th century, natural gas was primarily obtained as a by-product of producing oil. The small, light gas carbon chains came out of solution as the extracted fluids underwent pressure reduction from the reservoir to the surface, similar to uncapping a soft drink bottle where the carbon dioxide effervesces. The gas was often viewed as a by-product, a hazard, and a disposal problem in active oil fields. The large volumes produced could not be used until relatively expensive pipeline and storage facilities were constructed to deliver the gas to consumer markets.

Until the early part of the 20th century, most natural gas associated with oil was either simply released or burned off at oil fields. Gas venting and production flaring are still practiced in modern times, but efforts are ongoing around the world to retire them, and to replace them with other commercially viable and useful alternatives.

In addition to transporting gas via pipelines for use in power generation, other end uses for natural gas include export as liquefied natural gas (LNG) or conversion of natural gas into other liquid products via gas to liquids (GTL) technologies. GTL technologies can convert natural gas into liquids products such as gasoline, diesel or jet fuel. A variety of GTL technologies have been developed, including Fischer–Tropsch (F–T), methanol to gasoline (MTG) and syngas to gasoline plus (STG+). F–T produces a synthetic crude that can be further refined into finished products, while MTG can produce synthetic gasoline from natural gas. STG+ can produce drop-in gasoline, diesel, jet fuel and aromatic chemicals directly from natural gas via a single-loop process. In 2011, Royal Dutch Shell's 140,000 barrels (22,000 m3) per day F–T plant went into operation in Qatar.

Natural gas can be "associated" (found in oil fields), or "non-associated" (isolated in natural gas fields), and is also found in coal beds (as coalbed methane). It sometimes contains a significant amount of ethane, propane, butane, and pentane—heavier hydrocarbons removed for commercial use prior to the methane being sold as a consumer fuel or chemical plant feedstock. Non-hydrocarbons such as carbon dioxide, nitrogen, helium (rarely), and hydrogen sulfide must also be removed before the natural gas can be transported.

Natural gas extracted from oil wells is called casinghead gas (whether or not truly produced up the annulus and through a casinghead outlet) or associated gas. The natural gas industry is extracting an increasing quantity of gas from challenging, unconventional resource types: sour gas, tight gas, shale gas, and coalbed methane.

There is some disagreement on which country has the largest proven gas reserves. Sources that consider that Russia has by far the largest proven reserves include the US Central Intelligence Agency (47,600 km3) and Energy Information Administration (47,800 km3), as well as the Organization of Petroleum Exporting Countries (48,700 km3). Contrarily, BP credits Russia with only 32,900 km3, which would place it in second, slightly behind Iran (33,100 to 33,800 km3, depending on the source).

It is estimated that there are about 900,000 km3 of "unconventional" gas such as shale gas, of which 180,000 km3 may be recoverable. In turn, many studies from MIT, Black & Veatch and the US Department of Energy predict that natural gas will account for a larger portion of electricity generation and heat in the future.

The world's largest gas field is the offshore South Pars/North Dome Gas-Condensate field, shared between Iran and Qatar. It is estimated to have 51,000 cubic kilometers (12,000 mi3) of natural gas and 50 billion barrels (7.9 billion cubic meters) of natural gas condensates.

Because natural gas is not a pure product, as the reservoir pressure drops when non-associated gas is extracted from a field under supercritical (pressure/temperature) conditions, the higher molecular weight components may partially condense upon isothermic depressurizing—an effect called retrograde condensation. The liquid thus formed may get trapped as the pores of the gas reservoir get depleted. One method to deal with this problem is to re-inject dried gas free of condensate to maintain the underground pressure and to allow re-evaporation and extraction of condensates. More frequently, the liquid condenses at the surface, and one of the tasks of the gas plant is to collect this condensate. The resulting liquid is called natural gas liquid (NGL) and has commercial value.

Shale gas

Shale gas is natural gas produced from shale. Because shale's matrix permeability is too low to allow gas to flow in economical quantities, shale gas wells depend on fractures to allow the gas to flow. Early shale gas wells depended on natural fractures through which gas flowed; almost all shale gas wells today require fractures artificially created by hydraulic fracturing. Since 2000, shale gas has become a major source of natural gas in the United States and Canada. Because of increased shale gas production the United States was in 2014 the number one natural gas producer in the world. The production of shale gas in the United States has been described as a "shale gas revolution" and as "one of the landmark events in the 21st century."

Following the increased production in the United States, shale gas exploration is beginning in countries such as Poland, China, and South Africa. Chinese geologists have identified the Sichuan Basin as a promising target for shale gas drilling, because of the similarity of shales to those that have proven productive in the United States. Production from the Wei-201 well is between 10,000 and 20,000 m3 per day. In late 2020, China National Petroleum Corporation claimed daily production of 20 million cubic meters of gas from its Changning-Weiyuan demonstration zone.

Coal gas

Coal gas or Town gas is a flammable gaseous fuel made by the destructive distillation of coal. It contains a variety of calorific gases including hydrogen, carbon monoxide, methane, and other volatile hydrocarbons, together with small quantities of non-calorific gases such as carbon dioxide and nitrogen, and was used in a similar way to natural gas. This is a historical technology and is not usually economically competitive with other sources of fuel gas today.

Most town "gashouses" located in the eastern US in the late 19th and early 20th centuries were simple by-product coke ovens that heated bituminous coal in air-tight chambers. The gas driven off from the coal was collected and distributed through networks of pipes to residences and other buildings where it was used for cooking and lighting. (Gas heating did not come into widespread use until the last half of the 20th century.) The coal tar (or asphalt) that collected in the bottoms of the gashouse ovens was often used for roofing and other waterproofing purposes, and when mixed with sand and gravel was used for paving streets.

Synthetic natural gas

Synthetic natural gas (SNG), is a fuel gas (predominantly methane, CH4) that can be produced from fossil fuels such as lignite coal, oil shale, or from biofuels or using electricity with power-to-gas system. Gasification process is used to generate SNG. When the gasification is conducted with hydrogen in place of oxygen/air, it is called hydrogasification.

Renewable natural gas

Renewable natural gas (RNG), also known as biomethane, is a renewable fuel made from biogas that has been upgraded to a quality similar to fossil gas and has a methane concentration of 90% or greater.

Crystallized natural gas – clathrates

Huge quantities of natural gas (primarily methane) exist in the form of clathrates under sediment on offshore continental shelves and on land in arctic regions that experience permafrost, such as those in Siberia. Hydrates require a combination of high pressure and low temperature to form.

In 2013, Japan Oil, Gas and Metals National Corporation (JOGMEC) announced that they had recovered commercially relevant quantities of natural gas from methane hydrate.

Processing

The image below is a schematic block flow diagram of a typical natural gas processing plant. It shows the various unit processes used to convert raw natural gas into sales gas pipelined to the end user markets.

The block flow diagram also shows how processing of the raw natural gas yields byproduct sulfur, byproduct ethane, and natural gas liquids (NGL) propane, butanes and natural gasoline (denoted as pentanes +).

Demand

As of mid-2020, natural gas production in the US had peaked three times, with current levels exceeding both previous peaks. It reached 24.1 trillion cubic feet per year in 1973, followed by a decline, and reached 24.5 trillion cubic feet in 2001. After a brief drop, withdrawals increased nearly every year since 2006 (owing to the shale gas boom), with 2017 production at 33.4 trillion cubic feet and 2019 production at 40.7 trillion cubic feet. After the third peak in December 2019, extraction continued to fall from March onward due to decreased demand caused by the COVID-19 pandemic in the US.

The 2021 global energy crisis was driven by a global surge in demand as the world quit the economic recession caused by COVID-19, particularly due to strong energy demand in Asia.

Storage and transport

Due to its low density, it is not easy to store natural gas or to transport it by vehicle. Natural gas pipelines are impractical across oceans, since the gas needs to be cooled down and compressed, as the friction in the pipeline causes the gas to heat up. Many existing pipelines in the US are close to reaching their capacity, prompting some politicians representing northern states to speak of potential shortages. The large trade cost implies that natural gas markets are globally much less integrated, causing significant price differences across countries. In Western Europe, the gas pipeline network is already dense. New pipelines are planned or under construction between Western Europe and the Near East or Northern Africa.

Whenever gas is bought or sold at custody transfer points, rules and agreements are made regarding the gas quality. These may include the maximum allowable concentration of CO2, H2S and H2O. Usually sales quality gas that has been treated to remove contamination is traded on a "dry gas" basis and is required to be commercially free from objectionable odours, materials, and dust or other solid or liquid matter, waxes, gums and gum forming constituents, which might damage or adversely affect operation of equipment downstream of the custody transfer point.

Based on their geographic origin, H-gas (high-calorific gas) and L-gas (low-calorific gas) are to be distinguished. Both types require separate transport, leading to two separate pipeline networks, e.g. in parts of Germany (with a strengthened focus and transition towards H-gas, as the L-gas reservoirs in Germany and the Netherlands are declining).

Liquified natural gas

Compressed Natural gas

CNG is transported at high pressure, typically above 200 bars (20,000 kPa; 2,900 psi). Compressors and decompression equipment are less capital intensive and may be economical in smaller unit sizes than liquefaction/regasification plants. Natural gas trucks and carriers may transport natural gas directly to end-users, or to distribution points such as pipelines.

Flaring

In the past, the natural gas which was recovered in the course of recovering petroleum could not be profitably sold, and was simply burned at the oil field in a process known as flaring. Flaring is now illegal in many countries. Additionally, higher demand in the last 20–30 years has made production of gas associated with oil economically viable. As a further option, the gas is now sometimes re-injected into the formation for enhanced oil recovery by pressure maintenance as well as miscible or immiscible flooding. Conservation, re-injection, or flaring of natural gas associated with oil is primarily dependent on proximity to markets (pipelines), and regulatory restrictions.

Natural gas can be indirectly exported through the absorption in other physical output. The expansion of shale gas production in the US has caused prices to drop relative to other countries. This has caused a boom in energy intensive manufacturing sector exports, whereby the average dollar unit of US manufacturing exports has almost tripled its energy content between 1996 and 2012.

A "master gas system" was invented in Saudi Arabia in the late 1970s, ending any necessity for flaring. Satellite and nearby infra-red camera observations, however, shows that flaring and venting are still happening in some countries.

Similarly, some landfills that also discharge methane gases have been set up to capture the methane and generate electricity.

Salt domes and underground storage

Natural gas is often stored underground [references about geological storage needed]inside depleted gas reservoirs from previous gas wells, salt domes, or in tanks as liquefied natural gas. The gas is injected in a time of low demand and extracted when demand picks up. Storage nearby end users helps to meet volatile demands, but such storage may not always be practicable.

Floating liquefied natural gas

Floating liquefied natural gas (FLNG) is an innovative technology designed to enable the development of offshore gas resources that would otherwise remain untapped due to environmental or economic factors which currently make them impractical to develop via a land-based LNG operation. FLNG technology also provides a number of environmental and economic advantages:

Environmental – Because all processing is done at the gas field, there is no requirement for long pipelines to shore, compression units to pump the gas to shore, dredging and jetty construction, and onshore construction of an LNG processing plant, which significantly reduces the environmental footprint. Avoiding construction also helps preserve marine and coastal environments. In addition, environmental disturbance will be minimised during decommissioning because the facility can easily be disconnected and removed before being refurbished and re-deployed elsewhere.

Economic – Where pumping gas to shore can be prohibitively expensive, FLNG makes development economically viable. As a result, it will open up new business opportunities for countries to develop offshore gas fields that would otherwise remain stranded, such as those offshore East Africa.